Q.

Which of the following statements is not correct?

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a

Alcohols are weak acids as well as weak bases.

b

A primary alcohol on oxidation gives a carboxylic acid containing the same number of carbon atoms.

c

A secondary alcohol on oxidation gives a carboxylic acid containing the lesser number of carbon atoms.

d

The substitution of hydroxyl group by a halogen group in alcohol is an electrophilic substitution reaction.

answer is A.

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Detailed Solution

(a) Replacement of —OH by a halogen in an alcohol is nucleophilic substitution reaction. It is the protonated alcohol which acts as a substrate. 

(b) Alcohols are acidic enough to react with active metals to liberate hydrogen gas. They are basic enough to accept a proton from strong acids. 

(c) It gives a ketone containing the same number of carbon atoms. Further oxidation will give carboxylic acid containing lesser number of carbon atoms.

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