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Which of the following statements is not correct?

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The order of reactivity of halogen towards alkanes is $F_{2} > {Cl}_{2} > {Br}_{2}$

The reaction of ${Cl}_{2}$ and ${CH}_{4}$ proceeds via ionic mechanism.

Oxygen acts as an inhibitor in the reaction between ${CH}_{4}$ and ${Cl}_{2}$

Iodine does not react with ${CH}_{4}$ at all.

answer is B.

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Detailed Solution

(b) The reaction proceeds via free radical mechanism.

(d) It is due to the fact, that the reaction $I + {CH}_{4} \to HI + {CH}_{3}$ is highly endothermic $(Δ H^{\circ} = 138 kJ {mol}^{- 1})$

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