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Q.

Which of the following statements is not correct?

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a

The stability of carbocations follows the order: CH3+>CH3CH2+>CH32CH+>CH33C+

b

Nucleophilic substitution reaction involving SN1 mechanism may involve the inversion of configuration of carbon atom.

c

Nucleophilic substituion reaction involving SN2 mechanism is always associated with the inversion of configuration of carbon atom.

d

The CH33C˙ is more stable than CH32C˙H

answer is A.

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Detailed Solution

(a) The correct order is CH33C+>CH32CH+>CH3CH2+>CH3+

(b) In SN1 mechanism, a planar carbocation is formed. Attack of a nuclephile may occur from either sides of planar geometry. Thus, it may or may not lead to inversion. In fact, SN1 produces both types of configuration, inverted and noninverted.

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