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Which of the following statements is not correct for $S_{N} 1$ reactions?

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The reaction follows first-order kinetics

The nucliophile plays no role in the mechanism

The rate determining step is the conversion of transition state to the product.

The rate of reaction depends on the steric bulk of the alkyl group.

answer is C.

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Detailed Solution

(a) The rate expression is r = k [haloalkane]

(b) Nucleophile is involved in the fast reaction.

( c) Substrate ~ Transition state is the slow step.

(d) Steric bulk favours $S_{N} 1$ mechanism.

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