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Q.

Which of the following statements is not correct w.r.t. LCAO?

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a

ψMO = ψA ± ψB

b

Electrons in bonding molecular orbitals remain between the two nuclei most of the time there by decreasing the repulsion between nuclei

c

Electrons placed in bonding molecular orbitals tend to hold the nuclei together and stabilise the molecule.

d

The energy of bonding molecular orbital is always slightly higher than either of the atomic orbitals that have combined to form it.

answer is D.

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Detailed Solution

Bonding molecular orbitals always possess lower energy than  either of the atomic orbitals that have combined to form it.

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