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Q.

Which of the following statements is or are true?

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a

Due to frenkel defect, the density of the ionic solids does not changes

b

The volume of atoms present in a face centered cubic unit cell of a metal (r is atomic radii) is 163πr3

c

Two ions A+  and B have radii 88 pm and 200 pm respectively. In the close packed crystal of compound AB , the coordination number of A+  is 6

d

In CsCl crystal, edge length is 404 pm. The distance between the nearest neighbour is 350 pm.

answer is A, B, C, D.

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Detailed Solution

rc/ra=0.44,C.N=6;

CsClBCC:

 3a=4r 3a2=2r distance between neighbours=3a2

FCC:Z=4;4×43πr3

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