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Q.

Which of the following statements is/are correct?

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a

In Carius method, sulphur is oxidised to SO42ion with fuming HNO3

b

In Lassaigne's test, N present in the organic compound is converted into CN ions.

c

When an organic compound is heated with dry CuO and the gases evolved are passed through lime water which turns milky, the gas may be CO2 or SO2.

d

In Lassaigne's test for halogens, conc. HNO3 is used to remove HCN and H2S.

answer is A, B, C, D.

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Detailed Solution

HCN and H2S may interfere in halogen detection , if not removed

CuO will act as oxidising agent and convert C to CO2 

sulphur precipitated as BaSO4

L. extract will have NaCN

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