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Q.

Which of the following statement(s) is/are correct for ClO4  oxoanion?

 

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a

All Cl-O  bonds are identical and chlorine atom is sp3 hybridised

b

The chemical bonding takes place in ground state and charge dispersion is more than  ClO3 oxoanion.

c

It has total 4pπdπ  bonds between chlorine and oxygen.

d

It does not have any tendency of polymerisation

answer is A, C.

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Detailed Solution

ClO4 undergoes sp3 hybridization. Bonding occurs in its excited state which makes option 4 incorrect.

 The molecule do not have any tendency of polymerisation. Thus, option A and C is correct.

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