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Q.

Which of the following statements is/are correct regarding ${BrF}_{5}$ and ${BrCl}_{5}$ ?

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a

$∠ F - Br - F < ∠ Cl - Br - Cl$

b

Both have equal $X - B r - X$ bond angle

c

Both are isostructural

d

$∠ F - Br - F > ∠ Cl - Br - Cl$

answer is B, D.

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Detailed Solution

The bond angle of F-Br-F in ${BrF}_{5}$ is less than the bond angle of Cl-Br-Cl in ${BrCl}_{5}$ .

Both the molecule has same structural geometry. Thus, they are isostructural. Hence, option B and D are correct.

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