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Q.

Which of the following statements is/are correct regarding the Caro's acid?

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a

Hybridisation of S-atom is sp3d.

b

There is one peroxy linkage

c

It is dibasic acid but first proton will be released from peroxy linked O-atorn

d

It is dibasic acid but first proton will be released from OH group directly linked with S-atom.

answer is B, D.

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Detailed Solution

Caro's acid structure is,

Question Image

There is one peroxy linkage in this structure.

Caro's acid, is a dibasic acid as protons are attached to the oxygen of the hydroxyl group as well as perhydroxyl group.

Thus, option B and D are correct.

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