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Q.

Which of the following statement(s) is/are false regarding following reaction ?

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a

A nucleophilic substitution will take place in which only —CI attached on C1, will be replaced by —NH2,.

b

A nucleophilic substitution will take place in which  only -CI attached on C4, will be replaced by -NH2

c

No reaction is possible because —Cl is present on benzene ring.

d

A nucleophilic substitution will take place in which both —Cl will be replaced by two —NH2, groups.

answer is A, B, D.

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Detailed Solution

Recall that the —Cl group present in the o- and P- positions to the electron-withdrawing group is activated toward nucleophilic substitution, hence only —Cl present on the o- and/or p-position to  the —NO2, group will be replaced.

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Which of the following statement(s) is/are false regarding following reaction ?