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Q.

Which of the following statement(s) is/are true?

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a

If ΔHfH2O,g=242kJ/mol,ΔHvapH2O,1=44 kJ/mol than ΔfHOH,aq will be 142 kJ/mol

b

ΔfH (S, monoclinic) 0

c

If dissociation energy CH4(g) is 1656 kJ/mol andC2H6(g) is 2812 kJ/mol, then value of C-C bond energy will be 328 kJ/mol

d

ΔE=0 for combustion of C2H6(g) in a sealed rigid adiabatic container

answer is A, B, C.

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Detailed Solution

(a) q=0, W=0, U=0

(b) BE(CC)=281216564×6 =328

(c) 24244ΔHfOH=57.1

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