Q.

Which of the following statements is/are true.

A) Na2Cr2O7 is more soluble in water than K2Cr2O7.

B) K2Cr2O7 is used as a primary standard in volumetric analysis.

C) Both Na2Cr2O7 and K2Cr2O7 are strong oxidizing agents.

D) The chromates and dichromates are inter-convertible in aqueous solutions.

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a

A and D

b

All the above

c

A and B

d

B and C

answer is D.

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Detailed Solution

The statements are given.

A) Compared to K2Cr2O7 , Na2Cr2O7 is more water soluble(because solubility of dichromates of alkali metals decreases on going down the group)
B) The primary standard in volumetric analysis is K2Cr2O7 .
C) Na2Cr2O7 and K2Cr2O7 are both potent oxidizing agents.

D) In aqueous solutions, depending on the pH of the solutions, chromates and dichromates can be converted into one another.

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