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Q.

Which of the following statements regarding bond angles is/are true.

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a

among OSF₂, OSCl ₂, OSBr₂, halogen angle is least in OSF₂

b

among ${SbCl}_{3}, {SbBr}_{3}, {SbI}_{3}$ bond angle is least in ${SbCl}_{3}$

c

among $C_{2} H_{2}, C_{2} H_{4}, C_{2} H_{6}$ highest bond angle is in $C_{2} H_{2}$

d

the H-P-H bond angle in PH₃ is less than that in ${PH}_{4}^{+}$

answer is A, B, C, D.

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Detailed Solution

a) Due to small size of F atom, it has least bond angle
b) Due to small size of Cl atom, it has least bond angle
c) $C_{2} H_{2}$ has sp hybridization with bond angle 180
d) In PH₃, pure p-orbitals of phosphorus atom are involved in bonding. So bond angle is 90°

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