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Q.

Which of the following statements regarding lanthanides is not correct?

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a

Except  57La3+,58Ce4+ and  71Lu3 salts, all other compounds of lanthanides are paramagnetic

b

The compounds formed by lanthanides are covalent

c

The colour of the compound of lanthanide element having xf electrons is often similar to that of the element having ( 14 - x )f electrons

d

The pairs  40Zr and  72Hf,41Nb and  73Ta, and  42Mo and  74W have nearly identical sizes

answer is A.

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Detailed Solution

Ionic radii of trivalent lanthanides decreases with increase in atomic number due to lanthanoid contraction. The compounds formed by lanthanides are ionic. 

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