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Which of the following statements regarding phenols is not correct?

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o-Nitrophenol has a much lower boiling point as compared to p-nitrophenol

o-Nitrophenol can be steam distilled while p-nitrophenol cannot be.

o-Nitrophenol has much lower solubility in water as compared to p-nitrophenol

o-Nitrophenol is stronger acid than p-nitrophenol

answer is C.

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Detailed Solution

Statements C regarding phenols is not correct. o-Nitrophenol is stronger acid than p-nitrophenol

Because intermolecular hydrogen bonds make it exceedingly difficult to lose a proton, ortho nitrophenol is less acidic than para nitrophenol. In this sense, para nitrophenol is more acidic.

Hence option C is correct

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