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Q.

Which of the following statements(s) is/are correct?

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a

 SnCl2 does not hydrolyze

b

Tin (II) chloride is linear in shape

c

PbI4  is not known because of the oxidizing power of  Pb(+IV) and the reducing power of  I.

d

SnCl2  is reducing agent

answer is A, C.

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Detailed Solution

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I reduces  Pb(+iv) to  Pb(+2) because Pb is more stable in +2 than +4 state.
Sn+2  acts as reducing agent, hence SnCl2 reduces and converted into more stable form, SnCl4.

Tin (II) chloride has bent structure.

SnCl2 undergoes hydrolyzes and forms Sn(OH)Cl.

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