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Q.

Which of the following structures represents trans isomer.

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a

I, II, III

b

III, IV

c

II, III, IV

d

I, II

answer is A.

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Detailed Solution

 Cl (equatorial (e) and Br (axial) (a) (OR)
 Cl (downward) and Br (upward) Hence trans
II  Br (downward) (e) CH, (upward) (e) Hence trans
III  Both CH, and Br downward. Hence cis
IV  Both Br and Cl downward. Hence cis

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Which of the following structures represents trans isomer.