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Q.

Which of the following system has maximum number of the unpaired electrons in an inner orbital octahedral complex ?

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a

d4

b

d9

c

d7

d

d5

answer is A.

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Detailed Solution

There are four unpaired electrons in d4, d9 and d7 cannot form inner d-orbital complex, and for d5-there is only one unpaired electron in the presence of strong ligand and it does not form an inner orbital octahedral complex with a weak field ligand.

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