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Q.

Which of the following trihalide is stable?

         (1) NCl3                          (2) NI3

         (3) NBr3                          (4) NF3

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a

NCl3 

b

NI3

c

NBr3

d

NF3

answer is D.

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Detailed Solution

Nitrogen and Fluorine have comparable size, so when NF3 molecule formed, there is effective overlapping between N and F orbitals compared to other trifluorides of group-15 elements. This is the reason that NF3 shows high stability.

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