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Q.

Which of the following type of reaction occurs when 1-butyne reacts with HBr ? 

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a

Anti-Markownikoff’s radical addition

b

None of the above

c

Markownikoff’s electrophilic addition 

d

An electrophilic addition 

answer is B.

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Detailed Solution

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  • Addition in unsymmetrical alkynes takes place according to Markovnikov rule.
  •  Majority of the reactions of alkynes are the examples of electrophilic addition reactions.
  • CH3 CH2 CH2 CCH HBr   CH3 CH2 CH2 BrC=CH2   
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