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Q.

Which of the following will be the most stablediazonium salt $({RN}_{2}^{+} X^{-}) ?$

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a

${CH}_{3} N_{2}^{+} X^{-}$

b

$C_{6} H_{5} N_{2}^{+} X^{-}$

c

${CH}_{3} {CH}_{2} N_{2}^{+} X^{-}$

d

$C_{6} H_{5} {CH}_{2} N_{2}^{+} X^{-}$

answer is B.

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Detailed Solution

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Aliphatic amines do not give diazo compounds.
Benzene diazonium halide C₆H₅N⁺²X⁻ is most stable due to conjugation of the N≡N triple bond with benzene ring. Since, partial double bond character is present between C and N in benzenediazonium cation, so the removal of −N₂ is difficult

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