Which of the following will give a positive ${\mathrm{NaHCO}}_3$ test?

Ethanoic acid will give a positive ${\mathrm{NaHCO}}_3$ test.

Ethanoic acid exhibits effervescence in the presence of sodium bicarbonate which proves its acidic nature. On the other hand, ethanol shows no effervescence in the presence of sodium bicarbonate. This test is also used to prove the neutrality of alcohol.

The reaction taking place is 

${\mathrm{CH}}_3\mathrm{COOH}+{\mathrm{NaHCO}}_3\to {\mathrm{CH}}_3\mathrm{COONa}+{\mathrm{H}}_2\mathrm{O}+{\mathrm{CO}}_2$