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Q.

Which of the following will give PCl₅ ?

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a

Phosphorus (white or red) +SO₂Cl₂

b

PCl₅ + dry Cl₂ (excess)

c

Red or white phosphorus + dry Cl₂ (excess)

d

All of the above

answer is D.

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Detailed Solution

${PCl}_{3} + C l_{2} \overset{Δ}{\to} {PCl}_{5}$

$P_{4} + 10 C l_{2} \overset{Δ}{\to} 4 {PCl}_{5}$

$P_{4} + 10 {SO}_{2} C l_{2} \overset{Δ}{\to} 4 {PCl}_{5} + 10 {SO}_{2}$

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