Q.

Which of the following will give white ppt. with aq.AgNO3

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a

H2NCH2CH2CH2CH2Cl

b

PhCl

c

PhCH2I

d

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answer is D.

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Detailed Solution

Compound that releases Cl- can form white precipitate of AgCl.

White ppt. of AgCl with silver nitrate are produced by H2NCH2CH2CH2CH2Cl, as a result formation of a carbocation.

H2NCH2CH2CH2CH2Cl+AgNO3H2NCH2CH2CH2CH2++AgCl

The above carbocation can further rearrange to form a stable carbocation.

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