Q.

Which of the following will not be soluble in sodium bicarbonate?

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a

Benzenesulphonic acid

b

Benzoic acid

c

O-Nitrophenol

d

2,4,6-Trinitrophenol

answer is C.

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Detailed Solution

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ortho- nitrophenol is less acidic than expected due to intramolecular hydrogen bond. Hence it do not react with NaHCO3.

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