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Which of the following will not give orthoboric acid?

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B + HNO₃ (conc.)

B + H₂SO₄ (conc.)

B + HCl(conc.)

B₂H₆ + H₂O

answer is C.

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Detailed Solution

$B + 3 {HNO}_{3} \to H_{3} {BO}_{3} + 3 {NO}_{2}$

$2 B + 3 H_{2} {SO}_{4} \to 2 H_{3} {BO}_{3} + 3 {SO}_{2}$

$2 B + 6 HCl \to 2 {BCl}_{3} + 3 H_{2}$

$B_{2} O_{3} + 3 H_{2} O \to 2 H_{3} {BO}_{3}$

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