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Q.

Which of the following will not give positive test with CHCl3/KOH ? 

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a

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b

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c

CH3CH2NHCH3

d

CH3CH2CH2NH2

answer is A.

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Detailed Solution

carbyl reaction 

 R-NH2 +CHCl3+3KOHRN+C¯+3KCl+3H2O

primary / amine .

Thus, the correct option 1 is secondary amine.

does not give  carbyl amine test.

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