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Q.

Which of the following would have same magnetic nature whether sp mixing is operative or not?

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a

O2

b

All of these

c

C2

d

B2

answer is C.

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Detailed Solution

O2 have same magnetic nature whether sp mixing is operative or not,
When the energies of the s and p orbitals are comparable, s-p mixing takes place. As a result, the 2p orbitals for O have a greater energy than those for B and C. Because of this, B2 and C2 do have s-p mixing but O2 has very little (insufficient to modify the energy ordering).

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Which of the following would have same magnetic nature whether sp mixing is operative or not?