Q.

Which of the following yield both alkane and alkene

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a

Wurtz reaction 

b

Sandmeyer reaction

c

Kolbe's reaction

d

Williamsons synthesis 

answer is A.

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Detailed Solution

Kolbe's method : Electrolysis of a concentrated aqueous solution of either sodium or potassium salts of

carboxylic acids yields Alkanes/Alkenes at anode CH3COONaCH3COO+Na+

Anode : 2CH3COO2eCH3CH3+2CO3

Cathode : 2Na++2e-2Na,

 2Na+2H2O2NaOH+H2

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