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Q.

Which of the oxidation state(s) is/are shown by the element sulphur?

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a

+2 only

b

–2, +2, +4 and +6

c

–2, +2 and +4

d

–2 only

answer is D.

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Detailed Solution

Having a high electronegativity, oxygen. In most of its metallic oxides, it exhibits a -2 oxidation state, which indicates that it gains 2 electrons. Oxygen does not have room for unpaired electrons because it is tiny and lacks d-orbitals. A +2 oxidation state in OF2, a +1 oxidation state in O2F2, and a -1 oxidation state in hydrogen peroxide are examples of exceptions, though (H2O2 ). Sulfur Oxidation State
The size of sulphur is larger. It can expand its valency because its third d-orbital is vacant. Sulfur exhibits a -2 oxidation state in addition to +2, +4, and +6 oxidation states, the latter two of which are the most frequent.

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