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Q.

Which of the reaction defines  ΔHf0?

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a

N2(g)+3H2(g) 2NH3(g)

b

CO(g)+12O2(g) CO2(g)

c

C(diamond)  +O2(g) CO2(g)

d

12H2(g)+12F2(g) HF(g)

answer is B.

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Detailed Solution

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TIPS/Formulae:
ΔHfo is the enthalpy change when 1 mole of the substance is formed from its elements in their standard states.  In (a) carbon is present in diamond however, standard state of carbon is graphite. Again, in (d) CO (g) is involved so it can’t be the right option. Further in (c) 2 moles of NH3  are generated. Hence, the correct option is (b).

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