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Q.

Which of the reaction is expected to be spontaneous at low temperatures and non-spontaneous at high temperatures:

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a

Vaporisation of any volatile liquid

b

Dissociation of PCl5to give PCl3 and Cl

c

Formation of H2O from H2 (g) and O2 (g)

d

Melting of ice

answer is B.

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Detailed Solution

Formation of H2O from H2 (g) and O2 (g) is spontaneous at low temperature and non- spontaneous at high temperature.

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