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Q.

Which on of the following statements is not correct?

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a

The conjugate base of H2PO4- is H2PO42-

b

96,500 coulombs of electricity deposit one gram equivalent weight of copper from CuSO4 solution

c

The pH of 10-8 M HCL is 8

d

pH + pOH = 14 for all aqueous solutions

answer is B.

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Detailed Solution

HCl is a strong acid, so it will be having pH less than 7.

Since, the concentration of HCl is very less & along with acid there will be water molecules also present.

Therefore, [H3O+]total=[H3O+]acid+[H3O+]water -----(1)

HCL is completely ionized,

HCl(aq)+H2O(l)H3O(aq)++OH(aq)-

[H3O+]acid=1.0×10-8M

The concentration of [H3O+] from ionization is equal to [OH-] from water i.e [H3O+]water=[OH-]water=x

From (1) we get,  [H3O+]total=1.0×10-8+x

Since Kw=[H3O+][OH-]=1×10-14 ----(2)

Substituting value of [H3O+]total & [OH-] in (2), we get

(1.0×10-8+x)(x)=1×10-14

x2+10-8x-10-14=0, solving we get x=9.5×10-8

& pOH = -log[OH-] = -log[9.5×10-8] = 7.02

from equation pH + pOH = 14

                           pH = 14 – 7.02 = 6.98

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