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Which one among the following complex pairs possess different geometrical shapes

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${[Ni (CN)_{4}]}^{2 -} and {[{PtCl}_{4}]}^{2 -}$

${[Co {({NH}_{3})}_{6}]}^{3 +} and {[Co {({NH}_{3})}_{5} Cl]}^{2 +}$

${[{PtCl}_{2} ({en}_{2})]}^{2 +} and [Co {({en}_{3}]}^{3 +}$

${[Cu {({NH}_{3})}_{4}]}^{2 +} and {[{NiCl}_{4}]}^{2 -}$

answer is D.

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Detailed Solution

${[Cu {({NH}_{3})}_{4}]}^{2 +}$ is square planar while ${[{NiCl}_{4}]}^{2 -}$ is tetrahedral

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