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Q.

Which one is a wrong statement?

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a

Total orbital angular momentum of an electron in ‘s’ orbital is equal to zero.

b

An orbital is designed by three quantum numbers while an electron in an atom is designed by four quantum numbers.

c

The electronic configuration of N atom is

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d

The value of m for dz2 is zero.

answer is C.

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Detailed Solution

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According to Hund’s rule, unpaired electrons in degenarate orbitals must have same spin quantum number.
Nitrogen electronic confi juration 
Question Image
(1) Orbital angular momentum of electron
=ħI(I+l),ħ=h2π
Since for s-orbital, l=0, total orbital angular momentum of electron in s-orbital is equal to zero.
(2) An orbital is designated by three quantum numbers n, l, and m. An electron in an atom is designated by n,
l, m, and s quantum numbers. 
(4) The value of m for dz2 is zero because it is oriented along 90o with respect to the axis (cos 90o=0).

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