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Q.

Which one is the most likely structure of CrCl3. 6H2O if 1/3 of total chlorine of the compound is precipitated by adding AgNO3

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a

CrCl36H2O

b

CrH2O3Cl3H2O3

c

CrCl2H2O4Cl2H2O

d

CrClH2O5Cl2H2O

answer is C.

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Detailed Solution

The ions present in the ionisation sphere are precipited
Hence [CrCl2(H2O)4]Cl.2H2O contains 1/3 Cl in ionisation sphere to be precipited by AgNO3 as AgCl

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