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Q.

Which one is the most likely structure of CrCl3 6H2O if 23 of total chlorine of the compound is ppt by adding AgNO3 to its aqueous solution

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a

CrCl36H2O

b

CrCl2H2O4Cl2H2O

c

CrClH2O5Cl2H2O

d

CrCl3H2O33H2O

answer is C.

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Detailed Solution

By adding  AgNO3 23 of the compound's total chlorine is precipitated

Only one chloride ion is accessible for ionization due to the compound's aqueous solution 

CrClH2O5Cl2H2O

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Which one is the most likely structure of CrCl3.  6H2O if 23 of total chlorine of the compound is ppt by adding AgNO3 to its aqueous solution