Q.

Which one is the Swartz reaction from the following 

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a

CH3Br+Nal acetone CH3l+NaCl

b

CH3Br+Nal acetone CH3l+NaBr

c

CH3Br+AgFCH3F+AgBr

d

2CH3Cl+2Na Dry ether CH3-CH3+2NaCl

answer is C.

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Detailed Solution

  • When alkyl bromide or iodide are treated with metallic fluorides like AgF, HgF2​, etc., they form alkyl fluoride. 
  • This reaction is called Swarts reaction and is an important method for the preparation of fluoroalkanes.
  • CH3​Br + AgF → CH3​F + AgBr
  • It is a type of halogen exchange reaction.
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