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Q.

Which one of the following alcohol has highest boiling point

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a

Propanol

b

Butanol

c

Isopropanol

d

Isobutanol

answer is B.

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Detailed Solution

Linear molecules have more Boiling point than branched ones. As branching increases packing is poor and attractions are low.

Hence, Isopropanol<Propanol< Isobutanol<Butanol

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