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Q.

Which one of the following complex exhibits linkage isomerism ?

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a

CrH2O4Cl2Cl

b

CoNH35ONOSO4

c

PtNH34Cl2Br2

d

Cren2Cl2Cl

answer is B.

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Detailed Solution

Complexes containing ambidentate ligands exhibit linkage isomerism.

NO2,ONO,SCN,NCS,CN,NC are some important ambidentate ligands. 

CoNH35ONOSO4     and     CoNH35NO2SO4  are linkage isomers.

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