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Q.

Which one of the following complex ions has geometrical isomers?

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a

${[Ni {({NH}_{3})}_{5} Br]}^{+}$

b

${[Co {({NH}_{3})}_{2} {(en)}_{2}]}^{3 +}$

c

${[Cr {({NH}_{3})}_{4} (en)]}^{3 +}$

d

${[Co {(en)}_{3}]}^{3 +}$

answer is C.

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Detailed Solution

detailed_solution_thumbnail

	Complex	Isomerism shown
1)	${\|Co {(en)}_{3}\|}^{3 +}$	Optical only
2)	${\|Ni {({NH}_{3})}_{5} Br\|}^{+}$	No geometrical isomer
3)	${\|Co {({NH}_{3})}_{2} {(en)}_{2}\|}^{3 +}$	cis and trans
4)	${\|Cr {({NH}_{3})}_{4} (en)\|}^{3 +}$	No geometrical isomer

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Which one of the following complex ions has geometrical isomers?