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Q.

Which one of the following complexes exhibit chirality?

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a

cisRhCl2NH34+

b

Crox33

c

merCoNO23dien

d

cisPtCl2en

answer is A.

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Detailed Solution

  • The complex [Cr(ox)3​]3- contains no symmetry element and is chiral. 
  • It can be resolved into d and l forms.
  • The complexes cis−[PtCl2​(en)], cis−[RhCl2​(NH3​)4​]+and mer−[Co(NO2​)3​(dien)]  contain symmetry elements and are achiral.
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