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Q.

Which one of the following complexes is an outer orbital complex?

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a

[Fe(CN)6]4-

b

[Mn(CN)6]4-

c

[Co(NH3)6]3+

d

[Ni(NH3)6]2+

answer is D.

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Detailed Solution

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Fe(CN)64-d2sp3 Mn(CN)64-d2sp3 CoNH363+-d2sp3

The compound [Ni(NH3)6]2+ involves sp3d2 hybridization and is an outer orbital complex.

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