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Q.

Which one of the following complexes is an outer orbital complex?

[Atomic numbers: Mn= 25, Fe= 26, Co= 27, Ni= 28]

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a

Mn(CN)64

b

Fe(CN)64

c

CoNH363+

d

NiNH362+

answer is D.

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Detailed Solution

Outer orbital complexes are coordination compounds composed of a central metal atom having hybridization of the atomic orbitals including s, p and d orbitals from the outermost shell.

We have

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Thus, NiNH362+ + involves outer orbital complexation.

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Which one of the following complexes is an outer orbital complex?[Atomic numbers: Mn= 25, Fe= 26, Co= 27, Ni= 28]