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Q.

Which one of the following complexes is not expected to exhibit isomerism

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a

${[N i (e n)_{3}]}^{2 +}$

b

$[Ni {({NH}_{3})}_{2} {Cl}_{2}]$

c

${[Ni {({NH}_{3})}_{4} {(H_{2} O)}_{2}]}^{2 +}$

d

$[Pt {({NH}_{3})}_{2} {Cl}_{2}]$

answer is C.

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Detailed Solution

[Ni(NH₃)₂Cl₂] has tetrahedral geometry and thus, does not exhibit isomerism due to the presence of symmetry elements.

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