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Q.

Which one of the following compound undergoes disproportionation in the presence of concentrated KOH ?

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a

1-phenyl ethanone

b

3-phenyl propanal

c

Methanal

d

Cyclo pentane carbaldehyde

answer is A.

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Detailed Solution

Aldehydes (not ketones) not containing α-hydrogen atoms undergo disproportionation in presence of conc. alkali.

The reaction is called Cannizzaro's reaction.

(2), (3). . .contain α - hydrogen atoms.

(4) … ketone

1 2HCHO conc.KOH HCOO-K++CH3OH.

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