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Q.

Which one of the following compound will have higher boiling point

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a

Ethanal

b

Propanone

c

Propanal

d

Methanal

answer is B.

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Detailed Solution

In Carbonyl compounds the interactions between the molecules are dipole-dipole interactions.

Ketones are more polar than aldehydes. BP of ketones will be greater than corresponding aldehydes.

As already known BP increases with increase in MW.

BP of 2>1>3>4

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