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Q.

Which one of the following compounds shows the presence of intramolecular hydrogen bond?

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a

H2O2

b

HCN

c

Cellulose

d

Concentrated acetic acid

answer is C.

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Detailed Solution

Cellulose which shows the presence of intramolecular hydrogen bonding . This is due to the fact that the glucose monomers form straight chains and thus its polymeric structure crowd together showing intramolecular H-bonding.
However H2O2 also show intramolecular hydrogen but its is very weak due to large (O-OH) bond angle which produce repulsions and thus dominant H- bonding is not seen .

Hence , the correct option is (C).

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