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Q.

Which one of the following conditions will favour maximum formation of the product in the reaction

A2(g)+B2(g)X2(g),ΔrH=-X kJ?

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a

Low temperature and low pressure

b

Low temperature and high pressure

c

High temperature and low pressure

d

High temperature and high pressure

answer is A.

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Detailed Solution

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A2(g)+B2(g)X2(g),ΔrH=XkJ
Given, ng( pro )=2;ng( react )=1
According to Lechatelier’s principle,
(i) For an exothermic reaction, ΔH=ve ; decreases the temperature and shifts the equilibrium to right.
In other words, low temperature is favourable for high yield of the product (X2).
(ii) For a given reaction, pressure increases and equilibrium shifts in the forward direction; direction in which the number of moles of the gas decreases.

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